Document Details

Document Type : Article In Journal 
Document Title :
Catalytic activity of K10-montmorillonite in reaction of arenes with some mono- and di-functional alkylating agents, mostly derived from isobutane and isobutene
النشاط الحفزي الطيني K-10 خلال تفاعلات الآرينات مع بعض أحدي وثنائي المجموعة الوظيفية
 
Subject : Organic Chemistry 
Document Language : English 
Abstract : K10-montmorillonite was tested as Friedel-Crafts catalyst in the alkylation of benzene, toluene and anisole with one or more of the alkylating agents. The reaction products consisted essentially of 1,1-diaryl-2-methylpropane and 1,2-diaryl-2-methylpropane derivs. together with side products resulting from transalkylation, monoalkylation, hydride transfer and elimination. K10-montmorillonite was also used to catalyze the alkylation of naphthalene with benzyl alc. whereby a mixt. of - and -benzylnaphthalene were obtained. The results, explained in terms of carbocation transformations, show K10-montmorillonite to be a mild catalyst with no subsequent side-chain isomerizing ability just like FeCl3, AlCl3-CH3NO2, TiCl4 and ZrCl4. 
ISSN : 0376-4699 
Journal Name : Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry 
Volume : 35 
Issue Number : 2 
Publishing Year : 1416 AH
1996 AD 
Article Type : Article 
Added Date : Monday, June 23, 2008 

Researchers

Researcher Name (Arabic)Researcher Name (English)Researcher TypeDr GradeEmail
حسن عبدالقادر البارAlbar, Hassan AbdulkaderInvestigatorDoctoratehalbar@kau.edu.sa
سالم أ. باسيفBasaif, Salem A.ResearcherDoctoratehalbar@kau.edu.sa
على على خلفKhalaf, Ali AliResearcherDoctoratehalbar@kau.edu.sa

Files

File NameTypeDescription
 39092.pdf pdfكامل المقالة
 39093.pdf pdfمستخلص المقالة

Download This Page

Back To Researches Page