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Document Details
Document Type
:
Article In Journal
Document Title
:
Phase-Transfer Catalyzed Alkylation of Hydantoin and 5-Methyl-5-Phenylhydantoin
ألكلة هيدانتوين و 5-مثيل -5- فنيل هيدانتوين تحت ظروق حفز الانتقال الصنفي
Subject
:
Chemistry
Document Language
:
English
Abstract
:
PTC-alkylation of hydantoin (1a) and 5-methyl-5-phenylhydantoin (1b) by different organohalogen reagents at 25?C in the presence of tetrabutylammonium bromide as catalyst has been investigated either in the absence or presence of CS2. This work is aiming to study the comparative reactivity of N- versus O- of hydantoins toward alkylation and cycloalkylation. In all cases N3 monoalkylation or N1 and N3 dialkylation are the main products. The structures of alkylhydantoins have been established by IR, NMR, mass spectral data and elemental analysis.
ISSN
:
1012-1319
Journal Name
:
Science Journal
Volume
:
20
Issue Number
:
1
Publishing Year
:
2008 AH
2008 AD
Article Type
:
Article
Added Date
:
Tuesday, February 2, 2010
Researchers
Researcher Name (Arabic)
Researcher Name (English)
Researcher Type
Dr Grade
Email
طارق رشاد سبحي
Sobahi, Tariq R
Researcher
Doctorate
drtariq_s@hotmail.com
محمد علي حسين
Hassan, Mohamed A
Researcher
Doctorate
حسين أحمد مصطفى
Moustafa, Huissen A
Researcher
Doctorate
ناهد عمر باواكد
Bawaked, Nahed o
Researcher
Doctorate
Files
File Name
Type
Description
25028.pdf
pdf
Abstract
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