Document Details

Document Type : Article In Journal 
Document Title :
Catalytic activity of mesoporous catalysts in Friedel-Crafts benzylation of benzene
النشاطية الحفزيةللمواد الحفازة الميزومسامية في تفاعل فريدل كرافتز لبنزلة البنزين
 
Subject : Catalysis 
Document Language : English 
Abstract : Different samples of metal-incorporated MCM-41 were prepared and used as catalysts in Friedel-Craft's benzylation of benzene. The catalytic performance was evaluated by off-line GC analysis. Fe-MCM-41 exhibited excellent activity, the sample with Si/Fe ratio = 10 showed 90% conversion with 95% selectivity towards diphenylmethane within a few minutes. Generally, the activity per Fe-site was an order of magnitude higher for the samples containing a combination of Fe2O3 nano-particles and isolated Fe3+ sites. A synergy of two catalytic centers (particles and isolated sites) is proposed to explain the high performance of the highly loaded samples. The catalytic performance of Fe-MCM-41 was superior to other metal-containing MCM-41 (e.g. Ga, Sn, and Ti) catalysts, or other Fe-containing mesoporous materials (e.g. Fe-HMS 
ISSN : 13802224 
Journal Name : Journal of Porous Materials 
Volume : 16 
Issue Number : 5 
Publishing Year : 1429 AH
2009 AD 
Article Type : Article 
Added Date : Saturday, January 15, 2011 

Researchers

Researcher Name (Arabic)Researcher Name (English)Researcher TypeDr GradeEmail
احمد عرفات خميسKhamis, Ahmed ArafatInvestigatorDoctorateakhamis@kau.edu.sa
يحى ابو بكر الحامدAlhamed, Yahia Abou BakarInvestigatorDoctorateyalhamed@kau.edu.sa

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